Planar Chirality: A mine for catalysis and structure discovery

Planar chirality is one of the most fascinating expressions of chirality, exploited by Nature to lock three-dimensional chiral conformations and, more recently, by chemists to create new chiral reagents, catalysts and functional organic materials. Nevertheless, the shortage of protocols able to induce and secure asymmetry during the generation of these unique chiral entities has dissuaded chemists to exploit their structural properties. This Minireview intends to illustrate the limited but remarkable catalytic methodologies reported for the production of planar chirality in strained molecules and serve as source of inspiration for the development of new unconventional protocols that are expected to come in the near future.