(4,4′‐Dimethyl‐2,2′‐bipyridine)chloro‐(2,2′:6′,2′′‐terpyridine)‐iridium(III) hexafluorophosphate
2003
In the title compound, [IrCl(C12H12N2)(C15H11N3)](PF6)2, the ligand environment about the Ir atom is distorted octahedral. The 2,2′:6′,2′′-terpyridine (terpy) ligand is coordinated in a meridional fashion, the 4,4′-dimethyl-2,2′-bipyridine (dmbpy) ligand coordinated in a cis fashion and the Cl atom is trans to one of the dmbpy N atoms. Ir—N bond distances are 1.971 (5)–2.065 (6) A and the Ir—Cl distance is 2.357 (2) A.
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