A Combined Density-Functional and IRAS Study on the Interaction of NO with Pd Nanoparticles: Identifying New Adsorption Sites with Novel Properties
2008
Nanocrystalline particles expose special adsorption sites close to edges and corners, giving rise to novel adsorption and reaction properties. The spectroscopic identification of these sites represents a great challenge, however. Here, we present results of a combined experimental and theoretical study on the adsorption of NO on Pd nanoparticles, using infrared reflection absorption spectroscopy (IRAS) and calculations based on density-functional theory (DFT). This approach facilitates identification of the adsorption sites available on the nanoparticles and reveals detailed information on their bonding properties, on the vibrational parameters of NO adsorbed on these sites, and on their sequence of occupation. With respect to all these aspects, the adsorption behavior of NO on the Pd nanoparticles notably differs from any single crystal reference data available. The IRAS studies are performed on well-defined Pd nanoparticles supported on an ordered Al2O3 film on NiAl(110). The growth and structure of the...
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