Stereocontrolled Synthesis of Calyculin A: Construction of the C(1)-C( 14) Tetraene Nitrile Unit.

Anthony G. M. Barrett,Jeremy John Edmunds,James A. Hendrix,Kiyoshi Horita,Christopher J. Parkinson

Stereocontrolled Synthesis of Calyculin A: Construction of the C(1)-C( 14) Tetraene Nitrile Unit.

1992

Anthony G. M. Barrett
Jeremy John Edmunds
James A. Hendrix
Kiyoshi Horita
Christopher J. Parkinson

An enantioselective and geometrically selective synthesis of the C(1)–C(14) tetraene nitrile unit of calyculin A, using aldol chemistry with (+)-(E)-diisopinocampheylborane and Stille coupling, is described.

Keywords:

Calyculin A
Nitrile
Organic chemistry
Chemistry

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