Enhanced resolution of ultra micropore size determination of biochars and activated carbons by dual gas analysis using N2 and CO2 with 2D-NLDFT adsorption models

Abstract In this study, biochars obtained by either direct carbonization or hydrothermal treatment of corn stems were used as precursors of two series of activated carbons (ACs). The pore size distributions (PSDs) of biochars and ACs were evaluated from N 2 and CO 2 adsorption isotherms using models based on the two-dimensional version of the non-local density functional theory (2D-NLDFT). We showed that more detailed carbon PSDs might be obtained from simultaneous (dual) gas analysis of both N 2 and CO 2 isotherms than from single isotherms. The dual gas method showed a peak at about 0.4 nm which was not detected by the single N 2 analysis. This fact is related to the restricted diffusion of N 2 into very narrow micropores at low temperatures and pressures. By modifying the lower pore width limit w min in the nitrogen model, we obtained an excellent fit of the dual model to both isotherms for all studied samples, which demonstrates the reliability and robustness of this refined method. Finally, we demonstrated that this approach would allow measuring N 2 isotherms at relative pressures starting at about 0.001 rather than at 10 −6 , which would save time without losing resolution of the calculated PSD.