Synthesis of 2-(2-phenylethenyl) substituted 4,5-dihydrofurans byregioselective addition of 1,3-dicarbonyl compounds to dienes promoted by cerium(IV) ammonium nitrate
2016
Radical addition of 1,3-dicarbonyl compounds to conjugated dienes in the presence of cerium(IV) ammonium nitrate in THF produced 4,5-dihydrofurans in good to excellent yields. All radical additions occurred on the terminal double bond as regioselective. Two different dihydrofurans were obtained from the reaction of 1-phenyl-1,3-butanedione with 1-phenyl-1,3butadiene and 3-methyl-1-phenyl-1,3-butadiene. All compounds were characterised by IR, H, C-NMR and HRMS spectra.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
0
References
5
Citations
NaN
KQI