Weak C-H···O hydrogen bonds in anisaldehyde, salicylaldehyde and cinnamaldehyde.
2011
In situ cryocrystallization has been employed to grow single crystals of 4-methoxybenzaldehyde (anisaldehyde), C8H8O2, 2-hydroxybenzaldehyde (salicylaldehyde), C7H6O2, and (2E)-3-phenylprop-2-enal (cinnamaldehyde), C9H8O, all of which are liquids at room temperature. Several weak C—H⋯O interactions of the types Caryl—H⋯O, Cformyl—H⋯O and Csp3—H⋯O are present in these related crystal structures.
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