ENANTIOSELECTIVE SYNTHESIS OF AN ANT VENOM ALKALOID (-)-(3S-(3β,5β,8α))-3-HEPTYL-5-METHYLPYRROLIZIDINE

Seiichi Takano,Shizuo Otaki,Kunio Ogasawara

ENANTIOSELECTIVE SYNTHESIS OF AN ANT VENOM ALKALOID (-)-(3S-(3β,5β,8α))-3-HEPTYL-5-METHYLPYRROLIZIDINE

1984

Seiichi Takano
Shizuo Otaki
Kunio Ogasawara

An ant venom alkaloid (–)-[3S-(3β, 5β, 8α)]-3-heptyl-5-methylpyrrolizidine (1) has been synthesized in an enantioselective fashion from 3-(5-methyl-2-furly)propionaldehyde (2) employing enantioselective epoxidation at the key stage.

Keywords:

Alkaloid
Enantioselective synthesis
Ant venom
Organic chemistry
Chemistry

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