Geochemical Referencing of Natural Forest Contamination in Poland

Various studies have established possible threats posed due to pollution using ecological risk indices, but most have focused strictly on anthropogenic areas, so the data from these studies are less comparable with those obtained from natural forest sites, which was the focus of this current study. The main reason for this focus could be attributed to the commonly agreed reference provided by natural forest parks, which are assumed to be uncontaminated. The aim of this research was to determine if the Kampinoski National Park (Poland) could be considered a geochemical referencing ecosystem for Pb, Cd, and Ni levels. The specific purpose was to conduct a soil-background-based evaluation of metal contamination with a focus on geochemical indices as normative tools for assessing similar forest ecosystems at local and international levels. The toxicity response factors indicated some specific metal features that seemed highly magnified for Cd compared with Pb and Ni. The use of geochemical indices when assessing the contamination status of various ecosystems, either natural or strongly anthropogenic, is recommended to enable worldwide comparison, rather than only assessing metal contents. This approach considers the background metal concentrations for local on-site targets as well as pre-industrial reference levels for international referencing.