Spontaneous pattern transfer and selective growth of graphene on a Cu foil
2015
Abstract When a 25-μm-thick Cu foil placed on top of a selectively FeCl 3 -coated quartz substrate was heated inside a furnace at 1000 °C in a H 2 /Ar atmosphere, a FeCl 3 mask pattern on a quartz was spontaneously transferred to the front side of the Cu foil. Due to this spontaneous pattern transfer, a subsequent heating process in H 2 /Ar/CH 4 atmosphere led to selective growth of graphene on the front side of the Cu foil. Surface analysis revealed that a spontaneously transferred mask on a Cu foil was made of SiO 2 , and Si in SiO 2 was found to be from the quartz substrate. Computational simulation of surface diffusion of Si on a Cu foil was consistent with experimentally observed microstructures of spontaneously transferred pattern boundaries, which suggests that oxidation of diffused Si atoms, which originated from the FeCl 3 -coated region of a quartz, on the Cu surface was the crucial mechanism of the spontaneous pattern transfer.
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