Crystal structures, dielectric properties, and phase transition in hybrid improper ferroelectric Sr3Sn2O7-based ceramics

Hybrid improper ferroelectricity is induced by the coupling of oxygen octahedral rotation and tilt, and it may provide a promising way to develop new room-temperature single-phase multiferroic materials with a strong magnetoelectric effect. Though ferroelectric polarizations are confirmed by the electric hysteresis loops at room temperature, the ferroelectric-paraelectric phase transition has not been well understood. In the present work, the crystal structures, dielectric properties, and phase transition behaviors of Ruddlesden-Popper Sr3–xCaxSn2O7 ceramics are thoroughly determined. Ferroelectricity is confirmed through the polarization-electric field hysteresis loops at room temperature, and the Curie temperature is identified by the variable-temperature differential scanning calorimetric analysis and dielectric characterization. The polarizations and Curie temperatures of the present ceramics increase with increasing the calcium content. An improper ferroelectric transition is experimentally evidenced...