Chiral Version of the Burgess Reagent and Its Reactions with Oxiranes: Application to the Formal Enantiodivergent Synthesis of Balanol†
2008
An efficient formal synthesis of a (−)-balanol intermediate (25a) from cyclohexadiene oxide was accomplished in eight steps. An asymmetric version of the Burgess reagent allows for an enantiodivergent approach to both enantiomers of balanol from a racemic starting material.
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