Hydrochemistry and origins of mineralized waters in the Puebla aquifer system, Mexico

Significant upward movement of mineralized water takes place in the Puebla aquifer system. Preferential groundwater flow paths related to the geological structure and the lowering of the potentiometric surface are suspected to be the prime factors for this intrusion. A combined approach of geochemical and isotope analyses was used to assess the sources of salinity and processes that are controlling the changes in groundwater chemical composition in the Puebla aquifer. Geochemical and isotope data indicate that the likely source of increased solutes is mineralized water from the dissolution of evaporites of the Cretaceous age at the base of the Upper deep aquifer, which is deeper than the intakes of the shallow wells. Dedolomitization and cation exchange seems also to occur along flow paths where sulphate concentrations tend to increase. The deep regional flow paths controls the chemical stratification of groundwater in response to decreased heads through interconnecting vertical and horizontal pathways, such as in the Fosa Atlixco. The results also suggest that high sulphate concentrations originating in the Lower deep aquifer are currently affecting shallow production wells. It is concluded that hydrodynamic aspects together with hydrogeochemical characteristics need to be taken into account to correctly explain the hydrochemical evolution in the stratified aquifer.