Matrix‐Isolation Raman and Infrared Spectra, Molecular Structure, and Force Constants for XeO3F2

Both the Raman and the infrared spectra of low‐temperature matrix‐isolated molecules of XeO3F2 are reported. D3h symmetry for the molecules is indicated. The observed fundamental frequencies in cm−1 are 806.7 (a1′), 567.4 (a1′), 631.7 (a2″), 375.4 (a2″), 894 (e′), 318 (e′), 190 (e′), and 361 (e″). Force constants are reported in terms of the orbital valency force field assumption.