Naphtho[2,3-c]thiophene-4,9-dione based polymers for efficient fullerene solar cells
2020
Abstract Designing and synthesizing new organic photovoltaic materials is an inexhaustible driving force for the development of polymer solar cells (PSCs). For an excellent molecular structure with a certain conjugated skeleton, studying its analogues is of considerable significance for fully exploiting its photovoltaic potential. In this work, naphtho[2,3-c]thiophene-4,9-dione (NTD), an analogue of benzo[1,2-c:4,5-c’]dithiophene-4,8-dione (BDD), was designed and synthesized. Based on this building block, alkoxy side chains and alkylthio side chains were grafted on NTD to build NTD-O and NTD-S unit respectively, and then two new D-A conjugated donor polymers, PBNO and PBNS, were synthesized with NTD-O and NTD-S units as acceptor units and asymmetric benzodithiophene unit (asy-BDTBP) as donor units. Later, the photoelectric properties of these two materials in fullerene PSCs were studied. Compared with BDD based benzodithiophene copolymer (asy-BDTBP-BDD), PBNO and PBNS show similar LUMO energy levels, -3.59 eV and -3.63 eV, respectively, PBNO and PBNS show higher HOMO energy levels, which are -5.25 eV and -5.37 eV, respectively. PBNO blended with fullerene acceptor PC71BM exhibited similar power conversion efficiency (PCE) compared to the copolymer asy-BDTBP-BDD (4.64%). The PCE is 4.71% with short-circuit current density (JSC) of 9.85 mA cm-2, open-circuit voltage (VOC) of 0.784 V and fill factor (FF) of 60.98%. Encouragingly, PBNS presented an obviously enhanced PCE in PC71BM system PSCs, and PCE boosted to 7.58% (JSC, 12.40 mA cm-2; VOC, 0.865 V; FF, 70.83%). This work shows that analogues of excellent molecules have huge photovoltaic potential, and that side-chain modification has a significant impact on improving the photovoltaic performance of PSCs.
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