Direct Synthesis of Ultrathin Pt Nanowire Arrays as Catalysts for Methanol Oxidation.

High-performance electrocatalysts are of critical importance for fuel cells. Morphological modulation of the catalyst materials is a rare but feasible strategy to improve their performance. In this work, Pt nanowire arrays are directly synthesized with a template-less wet chemical method. The effects of surface functionalization and the reduction kinetics are revealed to be vital to the nanowire growth. The growth mechanism of the Pt nanowires is studied. By adjusting the concentration of the organic ligands, Pt nanowire arrays with tunable surface roughness can be obtained on various substrate surfaces. Such arrays avoid the contact resistance of randomly packed particles and allow open diffusion channels for reactants and products alike, making them excellent electrocatalysts for the methanol oxidation reaction. In particular, Pt nanowire arrays with rough surface have a mass activity of 1.24 A mgPt-1 at 1.12 V (vs Ag/AgCl), 3.18-fold higher than that of the commercial Pt/C catalysts. It also shows more resistant against poisoning, as indicated by the higher If /Ib ratio (2.06), in comparison to the Pt/C catalysts (1.30).