Extraordinary acceleration of phosphodiester hydrolyses by thorium cations
1997
Th
IV
cations in aqueous Brij micelles strongly promote the
hydrolyses of several phosphodiester substrates; in the case of
bis(p-nitrophenyl)phosphate 1, the observed rate constant (0.028
s
-
1
) represents an acceleration of ca
2.8 billion.
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