Photochemical deposition of noble metal ultrafine particles onto liposomes
1997
Composite particles consisting of liposomes loaded with silver or gold
ultrafine particles have been prepared by UV irradiation
(λ=253.7 nm) of AgClO
4
or NaAuCl
4
aqueous solutions in the presence of l-α-dimyristoyl
phosphatidylcholine liposomes. The diameter of the metal particles was
<5–7 nm. The absorption peak of the composite particles was
observed at λ=380–390 (silver) or 540 nm (gold). The
absorption spectra of the liposome/silver composite particles were broad
and weak. The quantum yield of photoreduction of silver ions increased in
the presence of liposomes. The usefulness of the liposome as a matrix for
loading and stabilizing the noble-metal ultrafine particles has been
demonstrated.
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