Sodium Borohydride—Nickel Chloride—Methanol Catalytic System for Regioselective Reduction of Electron-Rich Conjugated Dienes and Reductive Cleavage of Allyl Esters Involving π-Allylnickel Intermediates.

Biaolin Yin,Congbi Cai,Jin-Qiang Lai,Ze-Ren Zhang,Li Huang,Li-Wen Xu,Huanfeng Jiang

Sodium Borohydride—Nickel Chloride—Methanol Catalytic System for Regioselective Reduction of Electron-Rich Conjugated Dienes and Reductive Cleavage of Allyl Esters Involving π-Allylnickel Intermediates.

2012

Biaolin Yin
Congbi Cai
Jin-Qiang Lai
Ze-Ren Zhang
Li Huang
Li-Wen Xu
Huanfeng Jiang

The chemoselective reduction of one double bond of various electron-rich dienes, e.g. (I), (III), (V) and (XI) is smoothly achieved in the system NaBH4—NiCl2—MeOH.

Keywords:

Methanol
Conjugated system
Chloride
Nickel
Regioselectivity
Double bond
Polymer chemistry
Sodium borohydride
Catalysis
Chemistry
Organic chemistry

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