Self-supported Cu nanosheets derived from CuCl-CuO for highly efficient electrochemical degradation of NO3−

Abstract Degradation of NO 3 − into harmless N 2 is a significant challenge in the field of water treatment. In this work, 3D self-supported hierarchical electrode composed of ultra-thin Cu nanosheets-assembled micro-columns on porous nickel foam (Cu NSs/NF) was prepared by three steps, including electrodeposition of CuCl-Cu, thermal oxidation into CuCl-CuO and electrochemical reduction into Cu NSs. Benefitting from the advantages of large surface area and highly active interface as well as fast electron-transfer path, Cu NSs/NF exhibits the significant positive-shift of potential and higher current density than other Cu-based electrodes in the electrochemical reduction of NO 3 − (NO 3 − -ER). Not only that, an extremely high sensitivity of nitrate reduction response up to 11.23 mA mM −1  cm −2 was obtained by chronoamperometric test, which is much higher than those of previously reported works. Moreover, a conversion percentage of 99.7% for NO 3 − -ER was achieved on Cu NSs/NF cathode in NO 3 − -ER experiments. Finally, through the cathodic reduction of NO 3 − coupled with the anodic oxidation of Cl − , and the subsequent chemical reaction of NH 4 + and ClO − , the highly efficient degradation of NO 3 − into N 2 with selectivity as high as 97.2% was realized. This work provides a highly efficient Cu NSs/NF electrode and a promising way for degradation of NO 3 − into N 2 .