The First 1,4,2-Oxathiazolium Salts: Remarkable Similarities to Their 1,3,4-Isomers.
1992
Abstract 5-Methylmercapto-1,4,2-oxathiazoles, formed by 1,3-dipolar cyclo-addition between nitrile oxides and methyl dithiocarboxylates, are readily solvolysed with strong acid and an acyl anhydride to give in high yields the first examples of 1,4,2-oxathiazolium salts. Remarkable similarities betwen the 13 C NMR spectra of these and identically-substituted 1,3,4-oxathiazolium salts suggest that electronically the structures of the isomeric cations are very close.
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