Rate enhancements and secondary β-deuterium kinetic isotope effects as criteria of neighbouring group participation. Solvolysis of some tertiary alk-5-enyl chlorides

Mirko Orlović,K. Humski,S. Borčić,Eugenio Polla

Rate enhancements and secondary β-deuterium kinetic isotope effects as criteria of neighbouring group participation. Solvolysis of some tertiary alk-5-enyl chlorides

1986

Mirko Orlović
K. Humski
S. Borčić
Eugenio Polla

Rate enhancements in solvolysis of several of the title compounds are small or zero but significantly reduced secondary β-deuterium kinetic isotope effects indicate participation of the double bond.

Keywords:

Neighbouring group participation
Double bond
Kinetic isotope effect
Solvolysis
Reaction rate constant
Deuterium
Inorganic chemistry
Chemistry
Organic chemistry
Kinetic energy

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