LiCoPO4-3D carbon nanofiber composites as possible cathode materials for high voltage applications

2013 
Abstract Electrospun and carbonized 3D nanofiber mats coated with olivine structured lithium cobalt phosphate (LiCoPO 4 ) were formed by a Pechini-assisted sol–gel process as cathode material for lithium ion batteries. 3D nonwoven nanofibers were soaked in aqueous solution containing lithium, cobalt salts and phosphates at 80 °C for 2 h. Then, the composites were dried and annealed at 730 °C for 2 to 12 h in nitrogen atmosphere. Crystalline deposits were uniformly distributed on the carbon nanofiber surface. The “loading” of the cathode material on the 3D carbon nanofiber composites reached 300 wt%. The electrochemical measurements revealed the discharge specific capacity (measured at a discharge rate of 0.1 C and room temperature) reaching a maximum value of 46 mAh g −1 after annealing time t  = 5 h.
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