Bimetallic zeolite imidazolate framework for enhanced lithium storage boosted by the redox participation of nitrogen atoms
2018
In this work, a bimetallic zeolitic imidazolate framework (ZIF) CoZn-ZIF was synthesized via a facile solvothermal approach and applied in lithium-ion batteries. The as-prepared CoZn-ZIF shows a high reversible capacity of 605.8 mA h g−1 at a current density of 100 mA g−1, far beyond the performance of the corresponding monometallic Co-ZIF- 67 and Zn-ZIF-8. Ex-situ synchrotron soft X-ray absorption spectroscopy, X-ray diffraction, and electron paramagnetic resonance techniques were employed to explore the Li-storage mechanism. The superior performance of CoZn-ZIF over Co- ZIF-67 and Zn-ZIF-8 could be mainly attributed to lithiation and delithiation of nitrogen atoms, accompanied by the breakage and recoordination of metal nitrogen bond. Morever, a few metal nitrogen bonds without recoordination will lead to the amorphization of CoZn-ZIF and the formation of few nitrogen radicals.
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