Isotope Effects on Equilibrium Constants of Chemical Reactions; Transition State Theory of Isotope Effects

Max Wolfsberg,W. Alexander Van Hook,Piotr Paneth

Isotope Effects on Equilibrium Constants of Chemical Reactions; Transition State Theory of Isotope Effects

2009

Max Wolfsberg
W. Alexander Van Hook
Piotr Paneth

The statistical thermodynamic theory of isotope effects on chemical equilibrium constants is developed in detail. The extension of the method to treat kinetic isotope effects using the transition state model is briefly described.

Keywords:

Diatomic molecule
Physical chemistry
Kinetic isotope effect
Chemical reaction
Transition state theory
Kinetic energy
Chemical equilibrium
Equilibrium constant
Chemistry
Partition function (statistical mechanics)
Thermodynamics

Correction
Source
Cite
Save
Machine Reading By IdeaReader

References

Citations