The First Cationic Complex of Tetravalent Cerium

2011 
The recently reported cerium(IV) tripodal Schiff-base com- plex (TRENDSAL)CeCl (TRENDSAL = (N{CH2CH2N=CH(C6H2tBu2- 3,5-O-2}3) 3- ) serves as excellent starting material for novel Ce 4+ coordi- nation compounds. The first cerium(IV) azide, (TRENDSAL)CeN3 and
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