Assessment of Responses of Tropical Pacific Air–Sea CO2 Flux to ENSO in 14 CMIP5 Models

AbstractResponses of tropical Pacific air–sea CO2 flux (fCO2) to El Nino–Southern Oscillation (ENSO) events in 14 models from phase 5 of the Coupled Model Intercomparison Project (CMIP5) are examined. The contributions of sea surface temperature (SST), dissolved inorganic carbon in surface seawater (DIC), and total alkalinity of surface seawater (TALK) to interannual variation of ln(pCO2sea) (instead of partial pressure of CO2 in surface seawater pCO2sea) are quantified based on standardized empirical orthogonal function (EOF) results. Results show that six of the models have poor responses because they fail to reproduce observed interannual variation of pCO2sea in the central-eastern tropical Pacific. These six models underestimate the contribution of DIC interannual variation to interannual variation of pCO2sea in the central-eastern tropical Pacific due to a weak relation between interannual variation of upwelling and ENSO events or a weak relation (including no relation) between interannual variation ...