Oxidative Perhydroxylation of [closo‐B12H12]2‐ to the Stable Inorganic Cluster Redox System [B12(OH)12]2‐/·‐: Experiment and Theory.

Nguyen Van,Ioannis Tiritiris,Rainer F. Winter,Biprajit Sarkar,Priti Singh,Carole Duboc,Alvaro Muñoz-Castro,Ramiro Arratia-Pérez,Wolfgang Kaim,Thomas Schleid

Oxidative Perhydroxylation of [closo‐B12H12]2‐ to the Stable Inorganic Cluster Redox System [B12(OH)12]2‐/·‐: Experiment and Theory.

2011

Nguyen Van
Ioannis Tiritiris
Rainer F. Winter
Biprajit Sarkar
Priti Singh
Carole Duboc
Alvaro Muñoz-Castro
Ramiro Arratia-Pérez
Wolfgang Kaim
Thomas Schleid

The air stable, paramagnetic, sparingly water-soluble, solvent-free radical compound Cs[B12(OH)12] is synthesized in almost quantitative yield by perhydroxylation of Cs2[B12H12] with 30% H2O2 at 65 °C for six days.

Keywords:

Redox
Paramagnetism
Oxidative phosphorylation
Chemistry
Inorganic chemistry

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