Asymmetric Opening of Styrene Oxide with p‐Toluidine Catalyzed by BINOL Polyols and Their Lithium Complexes.

Yu. N. Belokon,Victor I. Maleev,M.A. Moskalenko,Yu. V. Samoilichenko,A. S. Peregudov,A. T. Tsaloev

Asymmetric Opening of Styrene Oxide with p‐Toluidine Catalyzed by BINOL Polyols and Their Lithium Complexes.

2014

Yu. N. Belokon
Victor I. Maleev
M.A. Moskalenko
Yu. V. Samoilichenko
A. S. Peregudov
A. T. Tsaloev

Opening of racemic styrene oxide with p-toluidine catalyzed by chiral BINOL-derived polyols proceeded regioselectively mainly with the formation of 2-phenyl-2-(p-tolylamino)-ethanol with low ee values.

Keywords:

Lithium
Catalysis
P-toluidine
Styrene oxide
Organic chemistry
Chemistry

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