Novel structurally characterized o-semiquinonato PCP-pincer nickel complexes

Konstantin A. Kozhanov,Michael P. Bubnov,N. N. Vavilina,Larisa Yu. Efremova,Georgy K. Fukin,V. K. Cherkasov,G. A. Abakumov

Novel structurally characterized o-semiquinonato PCP-pincer nickel complexes

2009

Konstantin A. Kozhanov
Michael P. Bubnov
N. N. Vavilina
Larisa Yu. Efremova
Georgy K. Fukin
V. K. Cherkasov
G. A. Abakumov

Structural study of dialkyl (PCP)-pincer o-semiquinonato nickel complexes indicated sloped relative positions of bi- and tri-dentate ligands. It became bright confirmation of propositions made on the base of their EPR spectra followed by molecular modelling.

Keywords:

Photochemistry
X-ray crystallography
Inorganic chemistry
Electron paramagnetic resonance
Ligand
Chemistry
Nickel
Pincer movement
Crystallography

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