Effect of rubbing on the molecular orientation within polyimide orienting layers of liquid‐crystal displays

The influence of various rubbing parameters on the molecular reorientation of thin polyimide orienting layers, used to align liquid‐crystal (LC) molecules within liquid‐crystal displays, has been studied. For this purpose the optical phase retardation in the polymer layer, explicitly induced during the rubbing treatment, was determined. The observed rubbing‐induced phase retardation can directly be related to a molecular orientation within the polymer orienting layer, as could be shown by infrared dichroism studies. Furthermore, it is found that the top of the polymer layer, directly contacting the rubbing cloth during the actual rubbing process, is almost instantaneously oriented to a certain maximum value as soon as the rubbing is started. Additional or stronger rubbing has no detectable influence on the orientation within the top layer. Increasing the rubbing density or the rubbing pressure only results in an increase of the penetration depth of the rubbing process, i.e., molecular reorientation occurs...