Highly Selective, High‐Capacity Separation of o‐Xylene from C8 Aromatics by a Switching Adsorbent Layered Material

: Purification of the C8 aromatics (xylenes and ethylbenzene) is particularly challenging because of their similar physical properties. It is also relevant because of their industrial utility. Physisorptive separation of C8 aromatics has long been suggested as an energy efficient solution but no physisorbent has yet combined high selectivity (>5) with high adsorption capacity (>50 wt %). Now a counterintuitive approach to the adsorptive separation of o-xylene from other C8 aromatics involves the study of a known nonporous layered material, [Co(bipy)2 (NCS)2 ]n (sql-1-Co-NCS), which can reversibly switch to C8 aromatics loaded phases with different switching pressures and kinetics, manifesting benchmark o-xylene selectivity (SOX/EB ≈60) and high saturation capacity (>80 wt %). Structural insight into the observed selectivity and capacity is gained by analysis of the crystal structures of C8 aromatics loaded phases.