Enantioselective Intramolecular Benzylic C—H Bond Amination: Efficient Synthesis of Optically Active Benzosultams.

Masami Ichinose,Hidehiro Suematsu,Yoichi Yasutomi,Yota Nishioka,Tatsuya Uchida,Tsutomu Katsuki

Enantioselective Intramolecular Benzylic C—H Bond Amination: Efficient Synthesis of Optically Active Benzosultams.

2012

Masami Ichinose
Hidehiro Suematsu
Yoichi Yasutomi
Yota Nishioka
Tatsuya Uchida
Tsutomu Katsuki

Iridium(III)—salen complexes (I) catalyze the title reaction of 2-ethylbenzenesulfonyl azides to give five-membered sultams with high enantioselectivities.

Keywords:

Enantioselective synthesis
Medicinal chemistry
Amination
Iridium
Hydrogen bond
Intramolecular force
Chemistry
Organic chemistry
c h bond
optically active

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