Tetravalent Manganese-Activated Near-Infrared Persistent Phosphors
2019
Persistent luminescence, also named long afterglow, is an interesting optical phenomenon where
a phosphor continues emitting for an appreciable time after the excitation source has finished.
Persistent phosphors or the glow-in-the-dark materials emitting in the visible spectral region have
drawn extensive attention and have achieved commercial success, for instance, SrAl2O4:Eu2+,
Dy3+ with green emission and CaAl2O4:Eu2+, Nd3+ with blue emission. Exploring persistent
phosphors in wavelengths beyond the visible spectral region, that is, in the near-infrared (650 to
900 nm), has been of great significance due to many promising advanced applications, ranging
from night-vision surveillance to medical imaging. In particular, the self-sustained feature of
near-infrared emitting persistent luminescence enables bio-imaging without external excitation,
without autofluorescence and with high signal-to-noise ratio. This state-of-the-art bio-imaging
technology has motivated the development of near-infrared emitting persistent phosphors with
high radiance and long duration.
Here, double perovskite type La2MgGeO6:Mn4+ phosphors were successfully prepared by an
energy-saving microwave-assisted solid state reaction method. This versatile synthesis is regarded as a rapid and cost-effective method to yield products with high homogeneity and purity. The La2MgGeO6:Mn4+ materials show strong emission in the deep-red and near-infrared spectral region, assigned to the transitions of tetravalent manganese ions. We are presenting a series of temperature dependent charging, afterglow and thermoluminescence measurements
trying to give clear information on the afterglow behavior and shed more light on the nature of the traps responsible
for the persistent luminescence.
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