Synthesis of Poly(aminoamides) via Enzymatic Meanst

Poly(aminoamides) constitute a subclass of polyamides that are water-soluble and useful for several applications. Commercially they are made via chemical reaction pathways. A review is made in this work of the enzymatic approaches towards their syntheses. Lipases and esterases have been found to be suitable enzymes to produce high-molecular-weight polyamides under relatively mild reaction conditions. A large number of different polymer compositions can be synthesized through enzymatic means. The design of the polymer structure and synthetic considerations are included in this review.