New copolymers for nonlinear optics applications that incorporate delocalized pi-electron subunits with well-defined conjugation lengths
1990
During the past three years it has become more evident that long conjugation sequences in electroactive materials may
not be a stringent requirement for high third order nonlinear optical (NLO) activity. Since long conjugation lengths in these
materials often make them difficult to process, the resulting insolubility often precludes the formation of optical quality films
for device applications. The incorporation of shorter electroactive segments alternating with flexible non-active spacers may
allow high NLO activity coupled with good optical film forming capability. In this paper we would like to present several
approaches to copolymer design which incorporate various electroactive oligomer segments with well-defined conjugation
lengths. The control one obtains in this appmach allows the design of sharp optical windows, and the ability to tailor
absorption characteristics to particular frequencies.
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