Halogén- és kéntartalmú oxianionok reakcióinak kinetikája és mechanizmusa = Kinetics and Mechanism of the Reactions of Some Halogen and Sulfur containing Oxyanions.

A kutatasi tamogatas negy eveben szamos, eddig ismeretlen, rendszer kinetikajat es mechanizmusat tanulmanyoztuk, vagy a korabbi ismereteket kiegeszitettuk, amellyel lehetőve valt az adott rendszer pontosabb leirasa. Az elert eredmenyek mindegyike a projektjavaslat ertelmeben kulonboző, kentartalmu szervetlen oxianion (szulfit, tioszulfat, tetrationat, pentationat) oxidacios reakcioinak kinetikai vizsgalatara korlatozodott. Mivel a vizsgalt rendszerek java resze modellreakciokent hasznalatos nemlinearis dinamikai jelensegek tanulmanyozasara, az uj ismeretek hozzajarulhatnak ezek pontosabb megismeresehez is. | The kinetics of several reaction system either with so far unknown mechanism (or kinetic model) has been studied during this 4-year project. In other cases the information about the given reaction system has been supplemented that allowed us to refine the kinetic model available in the literature. All the results accomplished were based on studying the kinetics and the mechanism of different sulfur containing oxyanions such as sulfite, thiosulfate, tetrathionate and pentathionate. Since majority of the systems investigated are used as a tool for studying nonlinear dynamical phenomena, the new information achieved in the frame of this OTKA project may contribute to better understanding of these phenomena as well.