Compressive Strain in N-Doped Palladium/Amorphous-Cobalt (II) Interface Facilitates Alkaline Hydrogen Evolution.

The development of palladium-based catalysts for alkaline hydrogen evolution reaction (HER) is highly desired for renewable hydrogen energy systems, yet still challenging due to the strong palladium-hydrogen bond. Herein, the bottleneck is largely overcome by constructing a nitridation-induced compressively strained-interface N-doped palladium/amorphous cobalt (II) interface (N-Pd/A-Co(II)), which dramatically boosts HER performance in alkaline condition. The optimized catalyst with the compressive strain of 2.7% exhibits the higher activity with an overpotential of only 58 mV to achieve the current density of 10 mA cm-2 , much better than those of pure Pd (327 mV), and the state-of-art Pt/C (78 mV). Notably, it also shows excellent stability with negligible decline during a 30 h stability test. Detailed analyses reveal that the strong absorption of Hads on Pd can be efficiently reduced via the compressively strained N-doped Pd. And the amorphous Co(II) component accelerates the water dissociation. Consequently, the cooperative effect between the compressed N-doped Pd and amorphous Co(II) creates the impressive HER performance in alkaline condition, highlighting the importance of the functional interface to develop efficient electrocatalysts for HER and beyond.