Selective Synthesis of Ethylbenzene and Styrene by Cross-Coupling Between Toluene and Methane over a Lithium-Promoted Y2O3-CaO Catalyst.
1991
Isotope-labelling experiments have shown that toluene oxidative methylation using methane to form C8 hydrocarbons over a lithium promoted Y2O3–CaO catalyst involves a cross-coupling between the methyl and benzyl radicals on the surface.
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