Molecular and electronic structure of several 2,3-dithienylquinoxalines and their 2:1 complexes with silver(I) nitrate
2014
We have synthesized three bis (thienyl) quinoxalinesilver(I)
complexes; however, unlike analogous silver(I) complexes of pyridylquinoxaline
that utilize (N, N) bidentate behavior from the quinoxaline and pyridyl ring
nitrogens, the bis(thienyl) quinoxaline ligands did not utilize the bonding potential
of the thienyl rings to give (N, S) bonding modes. PES spectra modeling of
these ligands indicates that the preferential metal bonding via only the
quinoxaline nitrogen atoms is due to the N-rich, but S-poor, characters of the
frontier orbitals.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
28
References
1
Citations
NaN
KQI