Synthesis of 1-Alkoxy-3,3-dialkyltriazene 2-Oxides from Alkoxyamines and Nitrosoamines.

The oxidation of O-alkylhydroxylamines by lead tetraacetate in the presence of dialkynitrosoamines leads to the 1-alkoxy-3,3-dialkyltriazene 2-oxides in yields up to 50%. The products were isolated by distillation. The chromato-mass spectrometric analysis of the reaction mixtures and compounds synthesized was carried out on an LKB-2091 spectrometer. The ionizing electron energy was 70 and 12 eV.