Copolymerization of N-Vinylsuccinimide with Butyl Acrylate in an Electron-Donor Medium of Tertiary Aminese

The effect of electron-donor solvents on the parameters of the NMR signals of vinyl protons in N-vinylsuccinimide and butyl acrylate was examined. The kinetics of copolymerization of N-vinylsuccinimide with butyl acrylate in triethylamine and tributylamine was studied by monitoring the running concentrations of the monomers in the course of the reaction. The copolymerization constants were calculated. The diad and triad composition of the copolymers formed in the medium of tertiary amines was predicted, and their microstructural nonuniformity was evaluated.