Organocatalytic Highly Enantioselective Substitution of 3-(1-Tosylalkyl)indoles with Oxindoles Enables the First Total Synthesis of (+)-Trigolutes B.

Jian‐Zhou Huang,Chen‐Long Zhang,Yi-Fan Zhu,Lu-Lu Li,Dian-Feng Chen,Zhi-Yong Han,Liu‐Zhu Gong

Organocatalytic Highly Enantioselective Substitution of 3-(1-Tosylalkyl)indoles with Oxindoles Enables the First Total Synthesis of (+)-Trigolutes B.

2015

Jian‐Zhou Huang
Chen‐Long Zhang
Yi-Fan Zhu
Lu-Lu Li
Dian-Feng Chen
Zhi-Yong Han
Liu‐Zhu Gong

The base promoted coupling of functionalized oxindoles (I) and (V) with 3-(1-tosylalkyl)indoles in the presence of bifunctional thiourea catalyst is developed.

Keywords:

Enantioselective synthesis
Bifunctional
Total synthesis
Organocatalysis
Catalysis
Organic chemistry
Chemistry
Thiourea

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