A Phenomenological Analysis of Sintering Mechanisms of W-Cu from the Effect of Copper Content on Densification Kinetics

The effect of addition of copper on the sintering of a W powder was systematically investigated by the analysis of dilatometric experiments on W and W-Cu compacts prepared with submicrometric powders. A pure W powder compact and a W-10 wt pct Cu powder compact with the same packing fraction of W particles were first studied, in order to analyze the effect of copper at fixed microstructure of the solid W particle packing. A more systematic set of experiments with different copper contents and W particle sizes was also qualitatively analyzed. A phenomenological model of sintering was developed and fitted in order to extrapolate the effect of copper content on sintering kinetics at fixed microstructure of the W particle skeleton. An interpretation of the sintering mechanisms was then proposed. Sintering of a W-Cu powder compact is the result of solid-state sintering of the W skeleton, enhanced by the capillary forces exerted by copper, with the superimposition of a particle rearrangement step after copper melting.