Photo transformation of 5-methylbenzotriazole and 5-chlorobenzotriazole by UV irradiation: Influences of pH, salinity, metal species and humic acid.

Abstract 5-methylbenzotriazole (5-TTri) and 5-chlorobenzotriazole (CBT) are two benzotriazole derivatives widely used in various industrial and domestic applications. This paper reports on the photochemical behaviour of 5-TTri and CBT in aqueous solutions under UV radiation at 254 nm and the influences of pH, salinity, metal species and humic acid (HA) on their photo-transformation processes. The photolysis of 5-TTri and CBT under the exposure to UV light were found to follow the first-order reaction kinetic in all cases with half-lives ranging from 7.1 h to 24.3 h for 5-TTri and 5.1 h–20.5 h for CBT in various aqueous solutions containing metal ions and HA. The photolysis rates for both 5-TTri and CBT were strongly dependent on the solution pH value, and decreased with increasing solution pH. Salinity, metal species Cu2+ and Fe3+, and especially HA had inhibitory effects on the photolysis of 5-TTri and CBT under UV light irradiation at 254 nm. We proposed the tentative photo transformation schemes for both 5-TTri and CBT, which involved two photoproducts (4-methylaniline and N, N-diethylaniline- p-toluidine) and three photoproducts (4-chloroaniline, Aniline and 2,6-diethylaniline), respectively, via N–N and N–NH bond scission and dechlorination process.