NMR study and electrical properties of (Cs)0.26(Rb)0.74H(SO4)0.89 (SeO4)0.11 mixed crystals
2005
Abstract Crystals of (Cs) 0.26 (Rb) 0.74 H(SO 4 ) 0.89 (SeO 4 ) 0.11 (CsRbHSSe) formulation are studied by 1 H NMR spectroscopy. The 1 H line-shape and the line width are determined as a function of temperature. The activation energy deduced from the temperature dependence of line width is compared with the activation energy issued from conductivity measurements by impedance spectroscopy. The results obtained are discussed and supported by the help of the Ngai model.
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