Gold(I)/Copper(II)-Cocatalyzed Tandem Cyclization/Semipinacol Reaction: Construction of 6-Aza/Oxa-Spiro[4.5]decane Skeletons and Formal Synthesis of (.+-.)-Halichlorine.

2015

The formal synthesis of halichlorine (XII) has been conducted via intermediate (XI) (1.5% overall yield over 11 steps) starting from compound (X).

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