All-Inorganic Perovskite Nanorod Arrays with Spatially Randomly Distributed Lasing Modes for All-Photonic Cryptographic Primitives.

The level of hardware or information security can be increased by applying physical unclonable functions (PUFs), which have a high complexity and unique nonreplicability and are based on random physical patterns generated by nature, to anticounterfeiting and encryption technologies. The preparation of PUFs should be as simple and convenient as possible, while maintaining the high complexity and stability of PUFs to ensure high reliability in use. In this study, an all-inorganic perovskite single-crystal array with a controllable morphology and a random size was prepared by a one-step recrystallization method in a solvent atmosphere to generate all-photonic cryptographic primitives. The nondeterministic size of the perovskite nanorods mainly arises from crystal growth in an indeterminate direction, producing a high entropy for the system. The cavity-size-dependent lasing emission behavior of perovskite single crystals was investigated as a preliminary exploration of the generation of all-photonic cryptographic primitives. The lasing-mode number was positively correlated with the length of the perovskite nanorods. Therefore, the prepared perovskite nanorod array with random sizes can be transformed into a quaternary cryptographic key array following encoding rules based on the lasing-mode number. Superior lasing stability was observed for the all-inorganic perovskite under continuous excitation, demonstrating the high reliability of this system.