Electrocatalytic Fluoroalkylation of Olefins. Perfluoroalkylation of 2‐Vinylpyridine.

Depending on the electrosynthesis conditions, perfluoroalkylation of compound (I) leads either to dimeric products of addition of perfluoroalkyl substituents at the double bond of the olefin (III) or, in the presence of triethylamine, to monomeric product (IV).