cis- and trans-Fused Di-Tetrahydropyrans by Rearrangement of Steroidal Spiroacetals.

2010 
Abstract A new method for the synthesis of steroidal cis- and trans-fused di-tetrahydropyrans (1,6-dioxadecalins) by reduction with DIBAH of derivatives of 1,6-dioxaspiro[4,5]decan-10-yl methanesulfonate is described.
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